content-type chemical/x-turbomole-vibrational is assigned to all non-empty files, which have a filename containing only three characters: https://github.com/dleidert/chemical-mime/blob/4fd66e3b3b7d922555d1e25587908b036805c45b/src/chemical-mime-database.xml.in#L1534 ``` % touch abc % echo test > bcd % cp /usr/share/wallpapers/Autumn/contents/screenshot.jpg cde % file abc abc: empty % file bcd bcd: ASCII text % file cde cde: JPEG image data, JFIF standard 1.01, resolution (DPI), density 299x299, segment length 16, progressive, precision 8, 400x250, components 3 % gio info -a 'standard::content-type' abc Adresse: file:///tmp/vibration/abc Attribute: standard::content-type: text/plain % gio info -a 'standard::content-type' bcd Adresse: file:///tmp/vibration/bcd Attribute: standard::content-type: chemical/x-turbomole-vibrational % gio info -a 'standard::content-type' cde Adresse: file:///tmp/vibration/cde Attribute: standard::content-type: chemical/x-turbomole-vibrational ``` This causes unexpected behavior, e.g. here: https://github.com/fwupd/fwupd/issues/1631